I am assuming that the 4-20 ma signal is linearly proportional to PH
values. This is usually the case with 2-wire PH transmitters, which it
sounds to me like you are using. If this is indeed the case, you
simply need to  subtract the 4 ma offset, and scale the remaining 16
ma proportionately to 0 to 14 ph. This also assumes that you have an
analog input capable of dealing with a 4-20 ma. current input. If you
have only voltage inputs, as most A/D cards have, then you have to use
a shunt resistor across the input of the A/D convert it to a voltage
signal.
Hope this helps.

Dave

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