That's explained in the "Sending Mail" page, here:
https://developers.google.com/appengine/docs/python/mail/sendingmail 
"The email address of the sender, the From address. The sender address must 
be one of the following types:

   - The address of a registered administrator for the application. You can 
   add administrators to an application using the Administration 
Console<https://developers.google.com/appengine/docs/adminconsole/index>
   .
   - The address of the user for the current request signed in with a 
   Google Account. You can determine the current user's email address with the 
   Users API <https://developers.google.com/appengine/docs/python/users>. 
   The user's account must be a Gmail account, or be on a domain managed by 
   Google Apps.
   - Any valid email receiving address for the app (such as 
   [email protected]).
   - Any valid email receiving address of a domain account, such as 
   [email protected]. Domain accounts are accounts outside of the Google 
   domain with email addresses that do not end in @gmail.com or 
   @APP-ID.appspotmail.com.

To send an email from an existing domain account, add the domain account as 
a Developer to your application using the Administration 
Console<https://developers.google.com/appengine/docs/adminconsole/index>. 
The account is then sent an email with an invite to develop the 
application, which you must accept to add the account to the application. 
It is possible that when you send emails from a domain account using Google 
servers, automated spam classifiers might believe the email address is 
being spoofed. If you run into this issue, set the SPF records for the 
domain to indicate that Google is a trusted source for your email. For 
instructions on how to do this, see SPF 
records<http://www.google.com/support/a/bin/answer.py?answer=33786> in 
the Google Apps help articles.
*Note:* Your domain (e.g. example.com) needs to be explictly registered 
with Google Apps and verified before you can create and use domain accounts 
(e.g. [email protected]). Domain accounts do not need to be explicitly 
verified, since you will have verified the domain during the registration 
process. For more information about registering a domain, see Register a 
new 
domain<http://support.google.com/a/bin/answer.py?hl=en&answer=53929&topic=20897&ctx=topic>
."

On Monday, July 16, 2012 8:34:34 AM UTC+2, Govind Chunchula wrote:
>
> Hi All,
>
>    I created an app in Google app engine and i am using the mail service 
> give by the app engine. Previousy i used the sender email Id as 
> [email protected] to send the emails. It is working fine. When i 
> wanted to change my sender email id its creating the error saying the 
> unauthorised sender. 
>
>    Previously i used [email protected] as sender email now i wanted to 
> move this to [email protected]. 
>
>    Please help me how to change this. 
>
> Thanks in advance.
>

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