"Jack Richard came to this conclusion years ago. He said Li-Ion batteries
work better hot. "

Years ago, before improvements in testing, that may have been applied to
"work better," but definitely, high temps are not a recipe for "works
longer."  Also "Li-ion" is far too broad a stroke for any pronouncement.
Some chemistries and formats should simply not be compared.
On Nov 17, 2015 9:47 AM, "dovepa via EV" <[email protected]> wrote:

>
> Jack Richard came to this conclusion years ago. He said Li-Ion batteries
> work better hot. It's in one of his videos I watched. I don't remember
> details but it was during all the Leaf problems in Arizona.
>
> Sent from my Verizon Wireless 4G LTE smartphone-------- Original message
> --------From: brucedp5 via EV <[email protected]> Date: 11/17/2015  2:19
> AM  (GMT-06:00) To: [email protected] Subject: [EVDL] A math formula can
> model li-ion pack aging, Pyrite pack
>
>
> 'Cheap-materials fool’s-gold pyrite battery'
>
>
> http://www.idtechex.com/research/articles/simple-mathematical-formula-models-lithium-ion-battery-aging-00008646.asp?donotredirect=true
> Simple mathematical formula models lithium-ion battery aging
> Nov 11, 2015  Penn-StateU,Volvo Group Trucks Technology
>
> Hybrid electric vehicles, cell phones, digital cameras, and the Mars
> Curiosity rover are just a few of the many devices that use rechargeable
> lithium-ion batteries. Now a team of researchers has a simple mathematical
> formula to predict what factors most influence lithium-ion battery aging.
>
> Lithium-ion batteries function by moving lithium ions from the negative
> electrode to the positive electrode and in the opposite direction when the
> battery charges. How often and exactly how that battery is used determines
> the length of a battery's life. Complex models that predict battery aging
> exist and are used for battery design. However, faster, simpler models are
> needed to understand the most important factors that influence aging so
> that
> battery management systems in hybrid electric vehicles, for example, can
> better control lithium-ion batteries.
>
> "We started out by making models specifically for Volvo's batteries that
> were tuned to their specific chemistry and showed that the models matched
> experimentally," said Christopher Rahn, professor of mechanical
> engineering,
> Penn State. "We then focused on simplifying the aging models. Now, we have
> the ultimate simplified aging model down to a formula."
>
> According to Rahn, a battery ages, or degrades, whether it is sitting on a
> shelf or used. The main cause of lithium-ion battery aging is the
> continuous
> formation of the solid electrolyte interphase (SEI) layer in the battery.
> The SEI layer must form for the battery to work because it controls the
> amount of chemical reactions that occur in the battery. As the battery is
> continually used, however, small-scale side reactions build up at the SEI
> layer, which decreases battery capacity -- how much of a charge the battery
> can hold. Models allow researchers to understand how different factors
> affect this degradation process so that longer-lasting, more cost-efficient
> batteries can be made.
>
> Hybrid electric vehicles combine the efficiency of electric vehicles with
> the power and longevity of gasoline-powered vehicles because they have both
> a gasoline-fueled conventional internal combustion engine and an electric
> motor powered by batteries. The electric motor uses regenerative brakes,
> which take the energy that was moving the car forward and convert it to
> mechanical energy, putting the electric motor into reverse and slowing down
> the car. The electric motor acts as a generator and takes the electricity
> that is generated to store in batteries for future use. This is in contrast
> to conventional braking systems in which braking energy is wasted when
> friction converts the energy into heat.
>
> According to the researchers, this new simple aging formula takes into
> account only the factors shown to most influence lithium-ion battery aging
> by affecting growth of the SEI layer, which include state of charge, how
> often the battery charges/discharges completely, operating temperature, and
> current.
>
> "Car companies can use this formula to quantify which factors are
> contributing the most in aging and focus more on them and less on all of
> the
> other factors that don't play as much of a role," added Tanvir Tanim,
> graduate student in mechanical engineering, Penn State.
>
> As part of the study, Tanim and Rahn compared the accuracy of their formula
> to that of more complex models using commercially available batteries. They
> found that their simple formula works just as well.
>
> "Whenever you simplify a model, there are some things lost," said Rahn. "We
> have complicated models because they are very accurate. As you simplify,
> you
> have to justify every assumption that you make. I wasn't sure we could
> simplify the model down to a formula. It's pretty amazing to explicitly see
> how things depend on one another."
>
> Rahn and Tanim have already seen the benefits of having a simple formula to
> model battery aging by using it to show that increasing the temperature of
> lithium-ion batteries in hybrid electric vehicles extends the life of the
> battery, which is contrary to what most researchers think. This effect was
> something that Volvo had previously seen with their batteries, and using
> this aging formula, Rahn and Tanim could explain why.
>
> Learn more at the next leading event on the topic: Electric Vehicles:
> Everything is Changing. USA 2015 [
> http://www.idtechex.com/electric-vehicles-usa/
> ] on 18 - 19 Nov 2015 in Santa Clara, CA, USA hosted by IDTechEx.
> [© idtechex.com]
> ...
>
> http://news.psu.edu/story/378093/2015/10/30/research/simple-mathematical-formula-models-lithium-ion-battery-aging
> Simple mathematical formula models lithium-ion battery ...
> Oct 30, 2015 - Now a team of Penn State researchers has a simple
> mathematical formula to predict what factors most influence lithium-ion
> battery aging.
>
>
>
>
> http://www.autoevolution.com/news/swiss-scientists-develop-cheap-battery-made-of-materials-that-are-abundant-102034.html
>  ... Colloquially called the “fool’s gold battery,” it consists of iron,
> sulfur, sodium and magnesium. Considering that all these elements are in
> plentiful supply, the experimental battery should be a lot cheaper than the
> ones currently on the market. This means that giant storage batteries could
> be built on the cheap and used stationary in buildings or next to power
> plants, for instance.
>
> The team of researchers, made of Maksym Kovalenko, Mark Walter, and their
> colleagues at Empa’s Laboratory of Thin Films and Photovoltaics, have
> combined a magnesium anode with an electrolyte made of magnesium and sodium
> ions. Nanocrystals made of pyrite - more commonly known as fool’s gold -
> serve as the cathode. Pyrite is a crystalline iron sulfide. Scientists have
> found that the sodium ions from the electrolyte migrate to the cathode
> during discharging. And when the battery is recharged, the pyrite
> re-releases the sodium ions.
>
> The result? Storing electricity. EMPA claims this so-called
> sodium-magnesium
> hybrid battery already works in the lab and has several advantages. For
> one,
> the magnesium as the anode is far safer than highly flammable lithium ...
> [© 2015 SoftNews NET]
>
>
>
>
> For EVLN EV-newswire posts use:
> http://evdl.org/evln/
>
>
> {brucedp.150m.com}
>
> --
> View this message in context:
> http://electric-vehicle-discussion-list.413529.n4.nabble.com/A-math-formula-can-model-li-ion-pack-aging-Pyrite-pack-tp4678722.html
> Sent from the Electric Vehicle Discussion List mailing list archive at
> Nabble.com.
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