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http://why.knovel.com/all-engineering-news/3462-recycled-lead-from-car-batteries-to-fuel-perovskite-solar-panels.html
Recycled lead from car batteries to fuel perovskite solar panels
August 18, 2014

[image  
http://pictures.brafton.com/new-research-from-MIT-will-soon-allow-for-the-recycling-of-depleted-car-batteries-by-turning-them-into-solar-panels_31_657401_1_14103206_900.jpg
(12V PbSO4 battery)
] ...

Most people know that you can recycle aluminum cans and plastic bottles, but
new research from MIT will soon allow for the recycling of depleted car
batteries by turning them into solar panels.

Old lead, new tech
Recently, Angela M. Belcher, PhD, Paula T. Hammon, PhD and a handful of
graduate students at MIT has described this novel system in the journal
Energy and Environmental Science. The science is based on the unique
properties of perovskite, a mineral that is making waves because of its
remarkable potential for solar panels. Perovskite, specifically, organolead
halide perovskite, has been used to great effect in making affordable,
highly efficient solar cells. In just a few years, perovskite went from
being an obtuse mineral, to one of the most promising materials in solar
research. Already, researchers have been able to make photovoltaic cells
that have close to a 19 percent power-conversion efficiency, which is nearly
equivalent with some of the best silicon-based solar cells currently
available on the market.

However, perovskite solar cells require the use of refined lead, which,
though relatively innocuous, needs to be processed from raw ore. This
procedure creates significant toxic residue, which has led early studies
into perovskite as a material for the construction of solar cells have
identified the use of lead as a major problem. However, by taking advantage
of abundant sources of refined lead from car batteries, this potential issue
becomes insignificant.

This research represents more than an alternative source of lead. If acted
on, this recycling method will reduce the number of car batteries dumped in
landfills significantly. More importantly, this is not a compromise or a
second-rate solution. Since the perovskite photovoltaic material is only a
thin film that is less than half a micrometer thick, the MIT research
demonstrates that the lead from a single car battery could produce enough
solar panels to power as many as 30 households. Perovskite solar cells are
fairly simple to produce, and it will be even easier if engineers can supply
their factories with recycled lead from batteries instead of needing to
refine it from raw ore.

Phasing out batteries
This comes at a fortuitous time for both the industries of solar panels and
automobiles. According to the U.S. Energy Information Administration, there
were 1,191,786 alternative fuel vehicles in use in 2011. That number has
risen significantly in the past three years, especially with the
introduction of electric car manufacturers like Tesla to the market. With
this technology trending, it is only a matter of time before old-fashioned
lead car batteries are a thing of the past.

According to Belcher, "Once the battery technology evolves, over 200 million
lead-acid batteries will potentially be retired in the United States, and
that could cause a lot of environmental issues."

Car batteries have been recycled for years, but according to the article, 90
percent of the lead recovered from recycled car batteries is used to make
new batteries. However, when the market for lead-acid batteries deflates,
then there will be no devisable purpose for depleted batteries. It is very
likely that without this research, many of those batteries would end up in
landfills where the lead would seep into ground water, causing significant
environmental problems in the surrounding areas.

If turned into solar panels, the lead would be fully protected by other
materials, such as perovskite. This would contain the lead, keeping it from
seeping and causing problems. When the solar cell is eventually retired, the
lead could easily be retrieved and recycled into new solar cells since the
lead would still be entirely reusable.

Belcher and her team hope that their solution to the lead problem will be
adopted by perovskite photovoltaics scientists, especially since their
research demonstrates that recycled lead is just as potent and usable as
freshly refined lead.

As more factories are beginning to consider the very real possibility of
mass producing perovskite solar panels in the near future, the potential for
the use of car batteries could be a game changer.

Solar power is one of the hottest new trends in alternative energy. Nearly
every state in the country has initiated some kind of solar incentive plan,
and it's not likely to slow down anytime soon. Perovskite solar panels will
make this technology even more widely accessible. By using recycled car
batteries, manufacturers will be removing toxic chemicals from landfills
while providing affordable green energy.
[© 2014 KNOVEL]
...
http://pubs.rsc.org/en/content/articlelanding/2014/ee/c4ee00942h#!divAbstract
Organohalide lead perovskites for photovoltaic applications
...
http://pubs.acs.org/doi/abs/10.1021/jp409025w
Organolead Halide Perovskite: New Horizons in Solar Cell Research




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