Looking for expert opinion, or better yet an ancient tome describing this 
phenomenon in detail.

 

 We have a contractor building a vehicle out of aluminum alloy, with no coating 
of any kind.  Standard practice in our industry is MIL-C-5541 class 3 chromate 
conversion coating when good rf bonding is required.

 

Concern is what happens with no coating.

 

My understanding until very recently was that absent the coating, the aluminum 
oxide that forms would act as an insulator at low voltages. That is, the issue 
of a MIL-B-5087 class H bond (shock hazard – green wire connection) is not at 
issue, because vehicle primary power voltage will punch right through the few 
nanometers of aluminum oxide.  But for class R (rf concerns) the oxide layer 
might look like an open circuit, because the rf potentials are millivolts, and 
cannot punch through. 

 

I procured a couple identical plates of 6061 aluminum, with the intent of 
dipping one of them, leaving the other uncoated, and measuring the difference 
in resistance across bonds with these sheets, using a milliohm meter with 
controlled applied voltage. The controlled voltage is worst case 20 mv, but 
with careful attention, can be held to 200 uV.  Careful attention was applied.

 

 To my surprise, I got single digit milliohm resistance across a bond between 
some copper shim stock and the bare, uncoated aluminum plate with no more than 
200 uV applied potential.

 

So the question is, is the chromate conversion only for environmental factors, 
such as salt fog? Or maybe to mitigate dissimilar metal connections? Is the 
fact that it is softer an aid in achieving a gas-tight spot?

 

Why are chromate conversion coatings almost universally applied to vehicle 
sheet aluminum?

 

Thank you,

 

-- 

 

Ken Javor

Ph: (256) 650-5261

 

 


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