Thanks for your report. Can you try to change the encoding in the preferences' editor preferences? I changed it to iso-8859-1 and a new mail I started to write had iso-8859-1 selected.
** Changed in: evolution (Ubuntu)
Assignee: (unassigned) => Ubuntu Desktop Bugs
Status: Unconfirmed => Needs Info
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Default Evolution encoding on new mail mesage
https://launchpad.net/bugs/40016
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