Is this partition in your /etc/fstab? If so, you cannot unmount it as
normal user.

If it is not in your fstab, please copy&paste the output of

  gnome-umount -vbd /dev/sdb2

and do

  lshal > /tmp/hal.txt

and attach /tmp/hal.txt here.

** Changed in: gnome-mount (Ubuntu)
       Status: New => Incomplete

-- 
Cannot unmount volume
https://bugs.launchpad.net/bugs/204844
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