I am having the same issue on Ubuntu 14.04. The problem seems to be that pgbouncer asks libssl (via libusual) to load a non existing file "/etc/ssl/cert.pem".
The configuration script for libusual tries to autodetect the CA file as either /etc/ssl/certs/ca-certificates.crt /etc/ssl/cert.pem The first file does exist, the latter does not. So it seems that build-time configuration for pgbouncer/libusual is not correct here. As a workaround, I created a symlink: /etc/ssl/cert.pem -> /etc/ssl/certs/ca-certificates.crt Greetings, Christian