I am having the same issue on Ubuntu 14.04.

The problem seems to be that pgbouncer asks libssl (via libusual) to load a non 
existing file "/etc/ssl/cert.pem".

The configuration script for libusual tries to autodetect the CA file as either

    /etc/ssl/certs/ca-certificates.crt
    /etc/ssl/cert.pem

The first file does exist, the latter does not. So it seems that build-time 
configuration for pgbouncer/libusual is not correct here.

As a workaround, I created a symlink:

    /etc/ssl/cert.pem -> /etc/ssl/certs/ca-certificates.crt


Greetings,
Christian

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