Sorry, if it's silly question - but I noticed the problem only recently, and
after digging around found these threads explaining roots of the problem:

 https://www.reddit.com/r/photography/comments/3q8q7o/purple_noise_in_shadows/
 
https://www.reddit.com/r/photography/comments/3q4tnz/how_to_correctly_push_5_stops_with_canon/

Not sure: have suggested there software tweaks been implemented into
Darktable already? Anyway if not - it could be worthy... it seems most of
the software - including Adobe's LR - handle Canon's RAW files not quite
correctly - that's why there are problem with unusual shadows' colours while
pushing.
-- 
regards,
Zbigniew
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