I can't offer many details on this, because the mists of time have descended, but I had an issue similar to this when I was moving all data off a file-based, deduplicated pool to a VTL-based pool. After all the data had apparently been moved to the VTL there were still volumes left with something on them. I opened a support case. TSM Support was able to confirm they were not data when I gave them the output of some select statements against DB2 tables that they provided. In the end, Support and I concluded that the remaining files on the File pool were orphan chunks from the deduplication process. After that I deleted the volumes because I need the LDEVs back for another purpose.
Best wishes, Keith Arbogast Indiana University